Lis, E. C.; Salomon, R. J.; Sabat, M.; Myers, W. H.; Harman, D. Synthesis of 1-Oxadecalins from Anisole Promoted by Tungsten. Journal of the American Chemical Society 2008, 130, 12472-12476.
Publications
2008
Kosturko, G. W.; Graham, P. M.; Myers, W. H.; Smith, T. M.; Sabat, M.; Harman, D. Tungsten-Promoted Diels−Alder Cycloaddition of Pyridines: Dearomatization of 2,6-Dimethoxypyridine Generates a Potent 2-Azadiene Synthon. Organometallics 2008, 27, 4513-4522.
Harrison, D. P.; Welch, K. D.; Nichols-Nielander, A. C.; Sabat, M.; Myers, W. H.; Harman, D. Efficient Synthesis of an η2-Pyridine Complex and a Preliminary Investigation of the Bound Heterocycle’s Reactivity. Journal of the American Chemical Society 2008, 130, 16844-16845.
2007
Welch, K. D.; Harrison, D. P.; Lis, E. C.; Liu, W.; Salomon, R. J.; Harman, D.; Myers, W. H. Large-Scale Syntheses of Several Synthons to the Dearomatization Agent TpW(NO)(PMe3) and Convenient Spectroscopic Tools for Product Analysis. Organometallics 2007, 26, 2791-2794.
Todd, M. A.; Sabat, M.; Myers, W. H.; Harman, D. [2+2] Cycloaddition Reactions with a Tungsten-Stabilized 2H-Phenol. Journal of the American Chemical Society 2007, 129, 11010-11011.
Liu, W.; Welch, K.; Trindle, C. O.; Sabat, M.; Myers, W. H.; Harman, W. D. Facile Intermolecular Aryl-F Bond Cleavage in the Presence of Aryl C-H Bonds: Is the η2-Arene Intermediate Bypassed?. Organometallics 2007, 26, 2589-2597.
Delafuente, D. A.; Kosturko, G. W.; Graham, P. M.; Harman, H.; Myers, W. H.; Surendranath, Y.; Klet, R. C.; Welch, K. D.; Trindle, C. O.; Sabat, M.; et al. Isomerization Dynamics and Control of the η2/N Equilibrium for Pyridine Complexes. Journal of the American Chemical Society 2007, 129, 406-416.
2006
Welch, K. D.; Smith, P. L.; Keller, A. P.; Myers, W. H.; Sabat, M.; Harman, D. Osmium(II)-, Rhenium(I)-, and Tungsten(0)-Promoted Dipolar Cycloaddition Reactions with Pyrroles: Exploiting the Azomethine Ylide Character of This Heterocycle. Organometallics 2006, 25, 5067-5075.
Todd, M. A.; Grachan, M. L.; Sabat, M.; Myers, W. H.; Harman, D. Common Electrophilic Addition Reactions at the Phenol Ring: The Chemistry of TpW(NO)(PMe3)(η2-phenol). Organometallics 2006, 25, 3948-3954.
Surendranath, Y.; Harman, W. D. The Role of Electrochemistry in the Development of π Basic Dearomatization Agents. Dalton Trans 2006, 3957.