A common feature of  d‐ and  p‐block elements is that they participate in multiple bonding.  In contrast, the synthesis of compounds containing homo‐ or hetero‐nuclear multiple bonds involving s‐block elements is extremely rare. Herein, we report the synthesis, molecular structure, and computational analysis of a beryllium imido (Be=N) complex (2), which was prepared  via  oxidation of a molecular Be(0) precursor (1) with trimethylsilyl azide Me₃SiN₃  (TMS-N₃ ). Notably, compound  2  features the shortest known Be=N bond (1.464 Å) to date . This represents the  first compound with an s‐block  metal−nitrogen multiple bond. All compounds were characterized experimentally with multi‐nuclear NMR spectroscopy ( ¹H,  ¹³C,  ⁹Be) and single‐crystal X‐ray diffraction studies. The bonding situation was analyzed with density functional theory (DFT) calculations,  which supports the existence of  π ‐bonding between beryllium and nitrogen.