Obi, A. D.; Deng, C.-L.; Alexis, A. J. H.; Dickie, D. A.; Gilliard Jr., R. J. Geminal Bimetallic Coordination of a Carbone to Main-Group and Transition Metals. Chemical Communications 2024, 60, 1880-1883.
Abstract
The non-bonding carbone lone pair in geometrically-constrained antimony and bismuth carbodiphosphorane complexes readily complexed AuCl to afford rare examples of geminal bimetallic carbone coordination featuring a main-group metal.