Walley, J. E.; Dickie, D. A.; Gilliard Jr., R. J. Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex. Zeitschrift fur Naturforschung B: Journal of Chemical Sciences 2020, 75, 497-501.
Abstract
Interest in beryllium, the lightest member of group 2 elements, has grown substantially within the synthetic community. Herein, we report the synthesis and crystal structure of a heteroleptic haloberyllium borohydride bis(1-isopropyl-3-methyl-benzimidazol-2-ylidene)methane ‘carbodicarbene’ (CDC) complex [(CDC)BeCl(BH4)]. Crystallographic data: Triclinic space group P1̅, a = 8.8695(14), b = 12.394(2), c = 16.844(3) Å, α = 102.395(4), β = 96.456(4), γ = 99.164(4)°, wR2 (all data) = 0.2706 for 6720 unique data and 357 refined parameters.