Brooks, B. C.; Chin, R. M.; Harman, W. D. The Asymmetric π-bases fac-Re(dien)(PPh3)(PF3)+ and fac-Re(dien)(PPh3)(CO)+: Evidence for Formation of an η2-Furan Complex. Organometallics 1998, 17, 4716-4723.
Publications
1998
1997
Winemiller, W.; Kopach, M.; Harman, W. The Protonation of Unactivated Aromatic Hydrocarbons on Osmium(II): Stabilization of Arenium Cations via Unprecedented η2- and η3-Coordination. Journal of the American Chemical Society 1997, 119, 2096.
Winemiller, M. D.; Kelsch, B. A.; Sabat, M.; Harman, W. D. The Characterization and Isomerization of η2-Naphthalene and η2-Phenanthrene Complexes of Pentaammineosmium(II). Organometallics 1997, 16, 3672.
Thompson, C. D.; Vachaspati, P. R.; Kolis, S. P.; Gulden, P. H.; Garst, M. E.; Wiese, A.; Munk, S. A.; Harman, D.; Macdonald, T. L. A Proposed Mechanism for p-Aminoclonidine Allergenicity Based on Its Relative Oxidative Lability. Chemical Research in Toxicology 1997, 10, 1032-1036.
Spera, M. L.; Harman, W. D. Electrophile-Promoted Carbon-Sulfur Bond Cleavage in η2-Thiophene Complexes of Pentaammineosmium(II). Journal of the American Chemical Society 1997, 119, 8843.
Spera, M. L.; Chen, H.; Moody, M. W.; Hill, M. M.; Harman, D. Electrophilic Addition to η2-Aldehyde Complexes of Pentaammineosmium(II): The Formation of Fischer Carbyne Complexes via η2-Aldehydium Intermediates. Journal of the American Chemical Society 1997, 119, 12772-12778.
Kolis, S.; Kopach, M.; Liu, R.; Harman, W. Osmium-Promoted Electrophilic Substitution of Anisoles: A Versatile New Method for the Incorporation of Carbon Substituents. J. Org. Chem. 1997, 62, 130.
Harman, W. D. The Activation of Aromatic Molecules with Pentaammineosmium(II). Chem. Rev. 1997, 97, 1953-1978.
Chin, R. M.; Dubois, R. H.; Helberg, L. E.; Sabat, M.; . Y. Bartucz, T.; Lough, A. J.; Morris, R. H.; Harman, W. D. The Preparation of Rhenium(I)-Amine and Rhenium(II) amine Dinitrogen Complexes and the Characterization of a Stretched Dihydrogen Species. Inorg. Chem. 1997, 36, 3553.
1996
Spera, M. L.; Chin, R. M.; Winemiller, M. D.; Lopez, K. W.; Sabat, M.; Harman, W. D. Sequential Electrophile/Nucleophile Additions for η2-Cyclopentadiene Complexes of Osmium(II), Ruthenium(II), and Rhenium(I). Organometallics 1996, 15, 5447.